Why are some inks more opaque than others?

Why are some printmaking inks more opaque than others? I’m currently working on a commission that won’t be unveiled until after it is delivered to its new collector. Without giving away the details, I found myself needing to shift from a middle blue tone into much darker greens. Enter the yellow opaque ink…

Gamblin’s Relief Ink Hansa Yellow Light is quite opaque.

Opacity vs transparency : not all inks are the same

After using Gamblin’s relief inks for a while, I intuitively know that yellow, napthol scarlet and titanium white will be the most opaque. Other inks like quinacridone red and phthalo blue will be very transparent. For me opacity means that it will cover up the color underneath more completely, and combine with it less. Even with opaque ink straight from the can, you will never get the color on the paper that you see on the glass. They aren’t completely opaque.

I wanted to answer the question of why some inks were more opaque than others. It was remarkably difficult to get such an explanation without jumping off into a discussion of physics for which I was not qualified.

Getting to the why of opacity and transparency

Mixing in some transparent blue didn’t make my yellow much less opaque.

Two on-line sources got me closer to an explanation of why inks vary in opacity. Why Some Paints are Transparent and Others Opaque, a page from Natural Pigments on-line store, has the most complete explanation. The Anatomy of Paint: Pigment and Binder from Essential Vermeer 2.0 has a discussion with a bit less physics.

The answer has three variables

Relative Refractive Indicies

Remember that all pigments whether naturally gathered or industrially created all start out as a powder. The powder is combined with a binder to allow the pigment to be applied to a surface. With printmaking, burnt plate oil (a heated version of linseed oil) is the binder.

Both pigments and binders have a rating for their ability to refract — or scatter — light. The more similar the number, the more likely the created ink will be transparent — or not scattering the light. Linseed oil has an index of 1.479 so pigments that have a very similar index will allow the most light to pass through, appearing transparent. Other pigments like zinc oxide, have an index of 2.00, and therefore appear opaque — not allowing any of the light through.

Particle Size

In my previous post on gold ink, I noted that my favorite one — Charbonnel’s Etching Ink Gold — had almost noticeable particles. It is very opaque, and this makes sense because the light is being refracted off the (larger) gold pigment particles, and can’t make its way down through the ink layers to the white paper.

Imagine all of those light particles struggling to make it through to the white paper!

Distribution of Pigment

This variable is obvious to me, as I liberally mix transparent base into my relief inks to increase the transparency of any color. Even still, I can never achieve the transparency of a phthalo blue with the yellow or white inks. This is probably because of the above two variables.

You can see that this mixed ink is fairly opaque because I can’t see any of the support buttons that are beneath the glass on the table,

I’m not sure I completely understand refractive indicies, but I do get a kick out of imagining the light rays trying mightily to penetrate my layer of ink and make it to the white paper.

Now back to my commission and to some new work. Science class is concluded.

Sneaking up on color

Were you one of those people who saw the Internet-featured dress as blue and black? Or were you in the white and gold camp? This was an example of color perception being relative — that color isn’t fixed, but changes depending on many factors. This makes finding the right next color layer a challenge for me. I have spent the last week or so sneaking up on the colors that I imagine for my next cloud-themed linocut. Here’s a portion of the linocut in progress:

Rosy colored cloud
Sunset illuminating clouds — in progress.

I’m exploring the effect that the setting sun would have on a blanket of clouds. I wanted the brightest parts to be either completely white or a warm yellow. The task then was to choose colors that will provide the dimensionality of the clouds, and then the dark (by contrast) blue and purple sky.

color chart
Watercolor chart created during election night for Bush v. Gore. I wonder if I will have some more nights like this during the current U.S. political season.

Intuitively, I want the lowest parts to have purple shadows, and the upper part to have a dark-greyed teal. But how to get there is the question. Purple over the yellow yields a rich brown, a color only associated with tornado clouds. I use this color chart to give me ideas of which way to head. I created this chart on the ill-fated election evening of the Bush vs. Gore election. Hour after hour we watched to see if a winner would be declared, and instead watched the newscasters flounder about in confusion. Mixing these watercolors kept me grounded.

My color challenges are two-fold. My sense is that the colors in the clouds should be transparent, so what color is beneath will directly affect the next color layer. In addition, what a color is next to greatly affects our perceptions. My favorite college art class (besides printmaking) was a color and composition class. Using a box of colored papers we were asked to create demonstrations that would fool the eye. Here are my two best examples:

pantone different looks same
Stripes of two different colors look the same when placed on different colored grounds.

In this example, the challenge was to take two different colors, and using different backgrounds convince the eye that it was seeing the same color. The colors I used are at the top, and then shown on top of two other colors. The illusion is helped by keeping the stripes away from each other.

pantone same looks different
Rectangles of the same blue green paper look markedly different on purple and yellow grounds.

In this example, the blue green paper is the same on each side, but your eye is challenged by the different color fields of purple and yellow.

I have probably two or three color layers left on my present linocut. Not much carving, but adding layers will more fully define the clouds and hopefully provide some more depth. To get to the darkest colors I may have to employ some more opaque ink, now that the cloud body is finished. I just hope I can accomplish on paper what I have had in my mind all along…

I do not intend to be opaque

I started out my adult art study with watercolors, a most unforgiving medium. Watercolor requires immediate commitment with the knowledge that it is difficult to undo what has been done. Yes, there is white, but it is opaque, unlike most watercolors. I was taught not to rely on it to fix my mistakes.

I’ve carried my aversion to opaque white into my printmaking. For the first few years I used only inks thinned with transparent base, gradually building up my image. This had two consequences that I didn’t like. First, the initial layers were by necessity short on chroma. I rarely accomplished a brilliant yellow. Second, it made using a complementary or split complementary color scheme very difficult. No matter how much purple you put over yellow, you are always going to get some kind of brown.

But all that has changed. I’ve started using opaque ink in places where I want rich colors, and don’t need that brilliant transparency of the white paper shining through the inks.

water 2 layer
Two layers of transparent blue, including a rainbow roll provide the base of the linocut.

I chose this watery pattern from a close-up of the Mosel River in Germany. I knew I didn’t want the blues to get darker, and I needed to switch to a different series of colors. Enter opaque white. Continue reading “I do not intend to be opaque”